Did you reflect the sun on to her? And you should fill in that Big white sky with blue on photoshop. Otherwise, good job.
No didn't reflect the sun. I never thought about changing the sky color... thanks.
Maybe next time when its that bright, try closing your appture by 1 or 2 stops.
Also try slowing or speeding up your shutter speed. And see what happens.
With her in shade use flash.